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Organocopper-based magnetically recoverable and reusable nanocatalyst for efficient synthesis of novel 1,2,3-triazole-based sulfonamides in green medium

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Abstract

We report robust green synthesis of novel 1,2,3-triazole-based sulfonamides bearing different motifs such as fluorine under click conditions in presence of a copper-based magnetically recoverable and reusable heterogeneous nanocatalyst. The organocopper catalyst at 0.5 mol.% was highly recyclable (up to five times) when recovered using an external magnet without significant loss in catalytic activity. The mild reaction conditions and excellent yields (69–95 %) make this protocol an attractive method for efficient synthesis of the title compounds. The structure of product 3a was determined by Röntgen crystal structure analysis.

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Notes

  1. Supplementary crystallographic data for 3a are available in CCDC-1456414. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data–request/cif.

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Acknowledgement

We are grateful to Mr. Biglari for NMR spectral support.

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Authors and Affiliations

  1. Department of Science, Payame Noor University (PNU), PO Box: 19395-4697, Tehran, Iran

    Hamid Saeidian, Hamed Sadighian, Masomeh Arabgari & Ezzatollah Najafi

  2. Department of Chemistry, Tehran Science and Research Branch, Islamic Azad University, Tehran, Iran

    Zohreh Mirjafary

  3. Department of Chemistry, Sharif University of Technology, PO Box 11155-9516, Tehran, Iran

    Seyed Ebrahim Ayati & Firouz Matloubi Moghaddam

Authors
  1. Hamid Saeidian
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  2. Hamed Sadighian
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  5. Seyed Ebrahim Ayati
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Correspondence to Hamid Saeidian.

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Saeidian, H., Sadighian, H., Arabgari, M. et al. Organocopper-based magnetically recoverable and reusable nanocatalyst for efficient synthesis of novel 1,2,3-triazole-based sulfonamides in green medium. Res Chem Intermed 44, 601–612 (2018). https://doi.org/10.1007/s11164-017-3122-1

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